287 research outputs found

    Compositionality and Statistics in Adjective Acquisition: 4-year-olds Interpret Tall and Short Based on the Size Distributions of Novel Noun Referents

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    Four experiments investigated 4-year-olds' understanding of adjective-noun compositionality and their sensitivity to statistics when interpreting scalar adjectives. In Experiments 1 and 2, children selected tall and short items from 9 novel objects called pimwits (1-9 in. in height) or from this array plus 4 taller or shorter distractor objects of the same kind. Changing the height distributions of the sets shifted children's tall and short judgments. However, when distractors differed in name and surface features from targets, in Experiment 3, judgments did not shift. In Experiment 4, dissimilar distractors did affect judgments when they received the same name as targets. It is concluded that 4-year-olds deploy a compositional semantics that is sensitive to statistics and mediated by linguistic labels.Psycholog

    Sources of Individuation in Mandarin Chinese, a Classifier language

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    PACLIC / The University of the Philippines Visayas Cebu College Cebu City, Philippines / November 20-22, 200

    A Small Fan and a Small Handful of Fans Exploring the Acquisition of Count-mass Distinction in Mandarin

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    PACLIC 19 / Taipei, taiwan / December 1-3, 200

    It’s in the Fine Print: Erasable Three-Dimensional Laser-Printed Micro- and Nanostructures

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    3D printing, on all scales, is currently a vibrant topic in scientific and industrial research as it has enormous potential to radically change manufacturing. Owing to the inherent nature of the manufacturing process, 3D printed structures may require additional material to structurally support complex features. Such support material must be removed after printing—sometimes termed subtractive manufacturing—without adversely affecting the remaining structure. An elegant solution is the use of photoresists containing labile bonds that allow for controlled cleavage with specific triggers. Herein, we explore state‐of‐the‐art cleavable photoresists for 3D direct laser writing, as well as their potential to combine additive and subtractive manufacturing in a hybrid technology. We discuss photoresist design, feature resolution, cleavage properties, and current limitations of selected examples. Furthermore, we share our perspective on possible labile bonds, and their corresponding cleavage trigger, which we believe will have a critical impact on future applications and expand the toolbox of available cleavable photoresists

    On the acquisition of maximality in free relative clauses and plural definite descriptions

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    Plural definite descriptions (e.g. 'the things on the plate') and free relative clauses (e.g. 'what is on the plate') have been argued to share the same semantic properties, despite their syntactic differences: both are non-quantificational expressions referring to the maximal element of a given set (e.g. the set of things on the plate). Experimental support for this semantic analysis is provided by the first investigation ever of children's interpretation of both constructions. A Truth-Value Judgment task, an Act-Out task, and a corpus study of children's linguistic input show that children are aware that the two constructions are different from quantificational nominals (e.g. 'all the things on the plate', 'some of the things on the plate') very early on (4 years old), despite the major difference in frequency in the input. Children acquire the adult interpretation of both constructions at the very same time, around 6-7 years old. We suggest that this relative delay depends on children's difficulties with the concept of the maximal element of a set or its association with specific linguistic constructions

    Unraveling the spontaneous zwitterionic copolymerization mechanism of cyclic imino ethers and acrylic acid

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    We report a high-resolution electrospray ionization mass spectrometric (HR ESI MS) access route leading to in-depths insight into the spontaneous zwitterionic copolymerization mechanism between cyclic imino ethers (i.e. 2-methyl-2-oxazoline (MeOx), 2-ethyl-2-oxazoline (EtOx) or 2-ethyl-2-oxazine (EtOz)) with acrylic acid (AA), exploiting the characteristic species accumulating during the copolymerization as well as tandem mass spectrometry (MS/MS). We demonstrate preferences in α,ω-end group formation by screening various feed ratios of cyclic imino ethers and acrylic acid (e.g. MeOx:AA = 1:1; MeOx:AA = 2:1; MeOx:AA = 1:2). Critically, a calibration curve – based on AA-MeOx-AA dimer – was established allowing for semi-quantitative determination of the end group ratios with different feed ratios of acrylic acid. The formation of, previously suggested, alternating copolymers was confirmed by MS/MS experiments. Deviations from an ideal alternating composition were found to decrease from MeOx to EtOx to EtOz. The results of (semi-quantitative) HR ESI MS and MS/MS measurements suggest, for the first time presented in such precision, a polymerization mechanism for the spontaneous zwitterionic (alternating) copolymerization indicating optimal monomer ratios and pairings

    Fully independent photochemical reactivity in one molecule

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    We introduce a chemically λ-orthogonal bichromophore triggered simply by different colours of light, enabling two different photochemical reactions in one molecule. Uniquely, the short wavelength (λ = 314 nm) does not trigger the red-shifted reaction system (λ = 416 nm), opening possibilities for the light controlled gating of specific molecular sites independent of wavelength.</p

    Adding chemically selective subtraction to multi-material 3D additive manufacturing

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    Existing photoresists for 3D laser lithography that can be removed after development in a subtractive manner typically suffer from harsh cleavage conditions. Here, we report chemoselectively cleavable photoresists for 3D laser lithography based on silane crosslinkers, allowing the targeted degradation of 3D printed microstructures under mild conditions. Three bifunctional silane crosslinkers carrying various substitutions on the silicon atom are synthesized. The photoresists are prepared by mixing these silane crosslinkers with pentaerythritol triacrylate and a two-photon photoinitiator. The presence of pentaerythritol triacrylate significantly enhances the direct laser written structures with regard to resolution, while the microstructures remain cleavable. For the targeted cleavage of the fabricated 3D microstructures, simply a methanol solution including inorganic salts is required, highlighting the mild cleavage conditions. Critically, the photoresists can be cleaved selectively, which enables the sequential degradation of direct laser written structures and allows for subtractive manufacturing at the micro- and nanoscale
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